Alternative Method for Making Lye, Part 4

     After working hard experimenting with the recipe in Part 3, I have discovered that recipe lacks water, or heat, or some vital process that makes it possible for completion. After some discovery on the internet, I was able to find a recipe for the reaction that seems to work out much better. The recipe comes from an interesting website that promotes the use of knowledge and technology to improve the lives of people worldwide, a noble challenge. They also have some great information about small and large livestock and crafts like candle and soap making.

      This is the mixture of hydrated lime and washing soda, after it has been boiled and is cooked and cooling. This pan is stainless steel, found at a rummage sale for $4, because I wasn't willing to risk one of my other pans to the process. Below is the first pan I tried making lye in, and it is hard to see from the picture, but the teflon is actually bubbled up off of the metal. Who would have thought? Teflon and calfalon are not of my favorite substances on the planet, after all the bad press they've received among the psittacine-phile communities for the deaths of hundreds of indoor pet birds. Apparently when teflon and its derivatives are heated above 200 degrees F, (which is every time you use it, right?) then toxic gases can be released which have been found to harm pet birds and newborns. That being said, don't make lye in a small enclosed room. Duh.
     I have still have to test the pH of the lye water that is produced from this process.

Alternative Method for Making Lye, Part 3

Barefootboy's Recipe and Method for making lye from washing soda and hydrated lime, originally found here. Edited by Tentance.

• Put 4 ounces of distilled water into two, 2-cup measuring cups (or containers).
• Slowly add 1/2 oz of the Sodium Carbonate to the water in the first cup and stir. It will clunk up, so you'll need to stir gently but well with each 1/2 oz you add. NOTE There will be some very minor but noticeable heat given off. This is normal. 
• Add 1/2 oz to the water until you reach 2 ounces. Stir until the mix is clear. There may be a tiny amount that will not mix. This is NOT a problem.
• Slowly add 1/2 oz of lime to the water of the second cup, stirring with each 1/2 added to mix as much as possible. Continue until you reach 2 oz. The mix will look like a grey white milk shake and there will be some gritty residue especially if you use garden lime. This also is not a problem.
• Carefully pour the first cup with the 4 oz of clear liquid into the first large container, leaving any non liquid behind.
• Now pour the second cup carefully into the first large container.
• The mix will now become an even thicker gray white mix. Allow to separate into a clear liquid and a white/grey solid. This can take 2 hours or more. General rule, if you can let it sit for 24 hrs, do so.
• Set up your funnel with filter on top of you second container.
• When the mix has settled, carefully pour off the clear liquid into the funnel.
• The first 3 to 3 1/2 ounces should filter off rather easily, the last 1/2 ounce will take a bit longer. You can either let the mix sit and separate over time, or put the white semi-solid in the filter and let sit until as much of the liquid as possible filters out. What will be left on the filter paper will be Calcium Carbonate (raw chalk) with lye residue. Dispose of this very carefully.

You should now have 4 oz more or less of at least 50% lye solution. Every batch has had the strength verified by the pH test and has turned out 13 on the scale.
As listed above 2 oz of Soda ash (Sodium Carbonate) to 4 oz of water and 2 oz of hydrated lime to 4 oz of water = 4 oz more or less of 50% lye solution.

 
Editor's Note: To calculate the amount of homemade lye to use in your soaps with your choice of oils, head over to the SoapCalc website. In field 1, choose NaOH (sodium hydroxide). In field 3, choose Lye Concentration 50%. Adjust your superfat and oil percentages and calculate as usual.
When in doubt, do a small test batch. You can always add more water and "cook" the soap for a longer amount of time in the crock pot or on your survival fire until you obtain the desired consistency. This homemade sodium hydroxide might lend itself more to the hot process method until you become more familiar with it.

Previous method discussion

Alternative Method for Making Lye, Part 2

This is an explanation of how to make common lye, sodium hydroxide, from readily available ingredients.
Explained very well by Barefootboy, from the Homesteading Today forum. Edited by Tentance.

Alternative Method for Making Lye 

     Due to the restrictions being placed on lye sold in stores because of the criminal use of it, I'd like to bring up an alternative method of making lye that does not require wood ashes.
     Get hydrated lime at a hardware store (as builder's lime) or garden supply store, it is used in gardening and I found it under the Hoffman brand. The next ingredient is a little trickier, you need to find some basic washing soap powder. It should be straight Sodium Carbonate with NO additives or perfumes. Arm and Hammer (Washing Soda) does sell it in the old blue box some of us remember for childhood, but most big box stores don't carry it. Try discount or dollar stores. I found 100% Sodium Carbonate being sold as a pool chemical inexpensively, called "Pool Time pH UP". Or, you could try heating regular baking soda (NOT baking powder) then use it as the soda ash. I'm not sure how long to heat it, as I have not tried that method, but chemically it's correct.
     If you do get these two, simply make an equal mix of each in filtered or distilled water and carefully combine. I suggest starting out with a cup of each to get used to the steps. This will create a white solid (Calcium Carbonate = chalk) and a liquid (Sodium Hydroxide = Lye). Using a funnel and a coffee filter, filter out the white solid.
     I mixed 1 tsp of the Sodium Carbonate with 3 oz of distilled water, and 1 tsp of the lime with 3 oz of distilled water. I poured them together and waited 5 minutes for the solid and liquid (lye) to separate, then filtered the mix through a coffee filter in a funnel. The result shows all signs of being Lye.
     This process does NOT require heating at any stage of it. It is simply dissolving two powders in enough water so they can mix and separate, and then filtering off the liquid. If you use 1 ( oz, cup etc) of each chemical (lime and carbonate) and 1 (oz, cup, etc) of water in theory you'll end up with 1 (oz, cup) of the solid and 2 (oz, cups) of the liquid which will be 50% strength lye (which may need to be further diluted with water to be used with a lye calculator).
     BUT as they said in MASH "this is meatball surgery" this is meatball chemistry, so you will not get the exactness you'd get under controlled lab or industrial conditions.
     On the other hand, it will work, and has signs of being economical (yield/cost) and IS an alternative to getting hassled whenever you want to make a batch of soap.
     I found that I had to use 2 cups of water to each cup of lime/carbonate (4 cups of water). I am filtering the mix now, and it's looking like I'll recover 2 cups of lye solution, so the 50% strength still looks viable. At the max I'll get 2.5 cups of lye solution, so that's still somewhere between 35 to 40%.

The fancy term for this is a "double displacement reaction" [Editor's Note: Double displacement reaction - aqueous metathesis (precipitation)]. The Sodium Carbonate swaps with the Calcium Hydroxide (slaked lime) to create Sodium Hydroxide (lye/liquid) and Calcium Carbonate (chalk/powder).

     Read more for a better recipe and breakdown of the method. Check out this post for confirmation of the validity of this method from a chemistry and soaping text.

     From PlicketyCat:

     You can grind limestone or seashells (calcium carbonate) and then heat it in a kiln/bonfire (1200F) until it calcinates and forms quicklime (calcium oxide), then soak the quicklime in water to create slaked lime (calcium hydroxide).
     You can also burn kelp/seaweed to create soda ash (sodium carbonate) instead of heating baking soda. Soak your soda ash with water and filter to leach out the carbonates, and mix that solution with our calcium hydroxide water solution to form Sodium Hydroxide (and dry calcium carbonate again).
     Or burn wood to create potash (potassium carbonate) and a small amount of soda ash (sodium carbonate). Soak the ashes with water and filter to leach out the carbonates, and mix that solution with your calcium hydroxide water solution to form Potassium Hydroxide (and dry calcium carbonate again).

Alternative Method for Making Lye, Part 1

     This is an excerpt from a chemistry text, written in 1856, called "A Treatise on Chemistry Applied to the Manufacture of Soap and Candles: Being a Thorough Exposition, in All Their Minutiae, of the Principles and Practice of the Trade, Based Upon the Most Recent Discoveries in Science and Art."
     I have taken enough college chemistry classes to realize that I never could seem to find the useful parts of the chemistry books. Perhaps because they didn't come with those chapters. But here is a small bit of a nifty chemistry which can be done at home to work-around the lack of available lye sources for home soaping.
     I love antique cookbooks and now, chemistry books. They provide a new perspective that is absent in our modern age.
     Read more for a more practical method breakdown. Do home chemistry at your own risk. Never throw salt in your eyes.
     What is soda ash? What is hydrated lime?

What is hydrated lime, really?

     Hydrated lime is a builder's concrete additive and a soil amendment. The high calcium, low magnesium (non-dolomitic) type can also be used for making a home-made version of sodium hydroxide by following the methods outlined here.
     The pure form of the chemical is known as calcium hydroxide (Ca(OH)₂) or slaked lime. It's pH is a high 12.4. Aglime and hydrated lime are frequently confused, but are chemically completely different. Aglime is crushed limestone (calcium carbonate).

     As a soil amendment, it is a cheap way to raise the pH of large amounts of overly acidic soil. In aquaponics and hydroponics, it can be used to safely raise adjust pH and add calcium to the closed systems, though some people would just add seashells to their system. There are several grades of hydrated lime for the garden, a high calcium grade, a medium calcium grade, and a dolomitic grade. These three are all varying degrees of magnesium added, with the high calcium having the least, and the dolomitic having the most.

    For the soap lye synthesis plan, I have found the highest calcium grade hydrated lime for the best price at the Sears website, of all places. Five pounds of 95% calcium for $13.63, free shipping. That's even cheaper than Amazon!

What is Soda Ash, really?

     Soda ash has been very popular in the do-it-yourself community. It is a household chemical that is considered to be very safe, and is chemically closely related to its cousin baking soda, though harder to find and slightly more expensive. It is used in laundry detergents, soaping, making glass, water softening, pool care, and for adding dye to clothing.
     Sodium carbonate (Na₂CO₃₎ is commercially made from common salt and limestone. It's pH is a high 11.6, compared to the more mild sodium bicarbonate (baking soda) of 8.4. The high pH and cheap production is what makes it valuable to water softening and pool care. It's unique chemical properties make it useful for laundry - "It competes with the magnesium and calcium ions in hard water and prevents them from bonding with the detergent being used" (Wikipedia). I have a nice recipe for the home-made laundry detergent here for your perusal.
     When used for home dye projects, it can help to mordant fiber-reactive dyes to vegetable fabrics. That
translates to binds certain synthetic dyes to fabric like cotton, hemp, or bamboo. It's usually used as a pre-mordant.
     When used in baking, it can replace baking powder/baking soda in order to leaven breads.
     When used to make glass, it is added to the mixture of salts and silica before the melt process is started. It hardens and makes the glass less permeable to water.
     For home swimming pools, it can be added to increase the water's pH which lessens the corrosive effects of chlorine. Indeed, finding sodium carbonate in the pool supply section of the local multi-mart can be the most cost effective way to purchase washing soda, with five pounds selling for under $15. 
     Historically, soda ash was made from leeching the ashes of certain seaweeds in a similar manner to potassium hydroxide production from wood ashes (read our post about it here). Before you ask, the common historically used plants were glassworts, saltworts, barilla, and seaweeds of the Fucus family (Wikipedia). Very little research has been done to investigate plant sources in the New World (maybe a survival project for another day?). It is mostly mined nowadays, but can be lab created in a similar manner as sodium hydroxide. 

Crock Pot Irish Soda Bread

      I had no idea that bread could be cooked in a crock pot. All the recipe books always said that bread needs to go into a preheated oven at the very least, 350 degrees F. So when I read about this technique at another website, I had to try it out for myself.

   It's simple - the crock pot is set on the highest setting with a grapefruit-sized dough ball (one pound of dough) for at least an hour. Any type of bread will work, but the crusts will be less crunchy than if they were cooked in a hot oven. I now no longer want to get a convection oven, and I can make small batches of bread without wasting all that electricity of using the oven.
     For this first experiment I used a modified Irish Soda Bread because I was so excited to try it out with the crockpot, and I certainly wasn't disappointed. I won't bore you with the details of the recipe, since I modified it anyway with semolina flour, oatmeal, and yogurt, but if you are interested in trying out a good and easy recipe, then I recommend the Best Beer Bread Recipe Ever. Just be sure to divide the dough in half so you don't overload the crockpot, which makes cooking time much longer. It lets you have another fresh loaf another day without doing any work.

     Put the dough ball on a large piece of parchment paper, and lower into the crockpot. Cover and bake or at least an hour on high. The crust will be soft when the bread is fully cooked, when its internal temperature reaches 190 degrees F. That's an hour and a half in my crockpot.

The Skinny on Irish Soda Bread

     I may have said before that I am a big fan of soda breads. They are cheap, quick, and easy to make, and don't require the addition of finicky yeast. Traditional Irish Soda Bread, a recipe that became popular during the Victorian Era, is the master recipe for many other quick breads.
     Irish soda bread is made with flour, buttermilk, baking soda, sugar, and salt. The traditional flour used for the recipe is a soft flour, the opposite of durum semolina. Soft flours are uncommon here in the US, but cake flour is a good mixture between soft and all-purpose that will work nicely if you are trying to closely approximate the historical recipe. I just use all-purpose, since that is what we buy in bulk and have for our longer term food storage/preps.
     Buttermilk is the only hard-to-get ingredient. It can be found in most grocery stores and tolerates freezing well, but if you don't have a chance to run out and pick some up, it can be approximated by adding some vinegar or lemon juice to plain milk. Yet another (traditional?) technique for approximating buttermilk when none is available is to use the effluent from a somewhat rancid sourdough starter as the buttermilk portion of the recipe. I see no reason why the effluent, or whey, from homemade yogurt couldn't be used in this way. All four additives could change the base recipe to suit your tastes. Which is your favorite?

Banana path update, one year later

     Remember the photo of these banana sticks that I planted last February?
     Surprisingly, all but one survived, and have turned into these beautiful, tropical trees. Photo taken in December.
     Underneath, on the southern side, I have decided to place another small sunken rabbit manure garden, planted up with taro, onions, annuals for the rabbits, and whatever else I can find.

Vitamin C for the Survivalist

     Have you ever thought about what your diet would be like if you had to fend for yourself? Have you found a solution to the problems of vitamin insufficiency in restricted diets? Most of our modern, processed foods have been vitamin-enriched to prevent scurvy, rickets, and folate deficiency. If you were trying to supply your whole diet from what you can grow or forage, would you be safe?

     Interestingly, capybaras and guinea pigs (cuys) also lack the ability to synthesize ascorbic acid just like humans, bats, and some other apes. If cuys are one of your survival protein sources or urban farming animal, this is a problem you will have to address.

     Lack of vitamin C results in scurvy, with significant symptoms appearing in as little as three months. Foods naturally high in ascorbic acid are cruciferous vegetables, all kinds of peppers, kiwi, seabuckthorn, acerola, goji berry, persimmon, and citrus. Also found in oysters and animal liver. Heat (cooking or canning) significantly reduces available vitamin C in foods. One trick for canning is to add lemon juice to foods which are lacking, increasing the vitamins, preventing oxidation, and lowering the pH.

     Although I have no real proof, I suspect that the leaves of many of our edible plants that produce high-vitamin crops probably have a higher than average concentration of those vitamins, particularly before flowering and fruiting. I suspect strawberry, rose, and hibiscus leaves to be higher in vitamin C, banana leaves to be higher in potassium, citrus leaves high in both. With our soils naturally being magnesium-deficient, I suspect that to be lacking in a person living on a native Floridian diet (in the absence of shellfish and other seafoods). The more research I have done to prove or disprove this hypothesis, the more I notice there is a lack of study in this area, though I did find here that purslane and plantain are very high in vitamin A precursor. This study finds that ascorbic acid is higher in lemon leaves than in the bark, roots, and juice, partially confirming my hypothesis.